Higher and foundation tiers

## Displacement reactions

Displacement reactions are a good way to demonstrate the order of reactivity of metals. In a displacement reaction a more reactive metal will remove or displace a less reactive metal from its compound or solution. The reactivity series for metals is shown lower down this page; it will help you work out what is happening in the equations below. You may notice that two non-metals, carbon and hydrogen have been included in the reactivity series. This is simply because these are two common reagents that are frequently reacted with metal compounds; often to extract metals from their ores.

Consider the following displacement reaction where a strip of zinc metal is dipped into a copper sulfate solution for about 60 seconds. When the strip of zinc is removed it will be covered in a thin layer of black copper powder (note copper metal is usually a bronze colour but damp copper powder appears black!).

 potassium sodium lithium calcium magnesium aluminium carbon zinc iron tin lead hydrogen copper silver gold platinum
In this reaction there are 2 metals present; copper and zinc. From the reactivity series shown opposite you can see that zinc is the more reactive metal of the two. In a displacement reaction the more reactive metal displaces the less reactive metal from its compound or solution, we can show this using a general formula to show what happens in a displacement reaction using the equation below:
##### Metal A + Metal B salt or solution → Metal A salt or solution + Metal B
So in this example the zinc metal will displace or remove the copper ions from the copper sulfate solution. Word and symbolic equations for this displacement reaction are shown below:
##### Zn(s) + CuSO4(aq) → ZnSO4(aq) + Cu(s)
An ionic equation is simply the symbolic equation with the charges on the ions shown, these ionic equations are helpful in identifying what has been reduced and what has been oxidised during a chemical reaction. The ionic equation for this reaction is:
##### Zn(s) + Cu2+SO42-(aq) → Zn2+SO42-(aq) + Cu(s)
Here you can see that the zinc atoms lose two electrons and form zinc ions (Zn2+) while the copper ions (Cu2+) gain two electrons and are reduced to form copper atoms. In this reaction the sulfate ion (SO42- )is a spectator ion; this means it remains unchanged in the reaction; it takes no part in the reaction. If we re-write the ionic equation but omit the spectator ions we have:
##### Zn(s) + Cu2+(aq) → Zn2+(aq) + Cu(s)
We can simplify this further by using half equations for each of the reactants:
##### Zn(s) → Zn2+(aq) + 2e this is an oxidation reaction
The zinc metal reacts to form zinc sulfate, an ionic compound containing zinc ions (Zn2+). The copper ions in the copper sulfate solution gain 2 electrons from the zinc and are reduced to copper atoms.
##### Cu2+(aq) + 2e → Cu(s) this is a reduction reaction
This is an oxidation/reduction reaction or a redox reaction. By combining the two half equations and cancelling out the electrons we get the overall equation for the reaction.

### More displacement reactions

Displacement reactions involving solutions are fun and safe to carry out in the lab. However reactions involving solids are much more violent and much more care is needed to ensure they are carried out safely. The diagram below illustrates the reaction between magnesium powder and copper oxide. Here the more reactive magnesium metal displaces or removes the less reactive copper from the solid copper oxide. This reaction is very violent!

Equations for this reaction are:

##### Mg(s) + CuO(s) → MgO(s) + Cu(s)
The further apart the two metals are in the reactivity series the more violent and explosive the reactions become. If the copper oxide in the above reaction is replaced with silver nitrate then an explosive reaction occurs, this reaction is extremely violent and a large amount of heat and light is released in the resulting explosion. The reaction is more violent since the two metals involved; silver and magnesium are further apart in the reactivity series. Once the two reactants are mixed a simple drop of water will cause this explosive reaction to start, there is no need to heat the mixture. The reaction can be summarised as:
##### Mg(s) + 2AgNO3(s) → Mg(NO3)2(s) + 2Ag(s)

In both these examples the more reactive metal is oxidised, it loses electrons and the less reactive metal is reduced, it gains electrons. These reactions are displacement reactions but they are also redox reactions.

### Using hydrogen gas to displace unreactive metals

Hydrogen, though not a metal reacts in many cases as if it was a metal. In terms of reactivity hydrogen sits just above copper in the reactivity series. This means that it can be used to displace any metal below it in the reactivity series such as copper or silver. The image below shows how copper oxide can be reduced to copper metal using a stream of hydrogen gas from a cylinder.

Equations to show this displacement reaction are shown below:

## Key Points

• A displacement reaction is one where a more reactive metal will remove a less reactive metal from its compounds or a solution.
• The more reactive metal is oxidised and the less reactive metal is reduced in a displacement reaction