Header image metal acid reactions

Higher and foundation tiers

Metal acid reactions

Self-check

What simple test can be used to identify hydrogen gas?
Use the pop test. If a lit splint is place near the mouth of a test-tube containing hydrogen it will burn with a pop.
What ion is present in all acids?
Hydrogen ions are found in all acids.
What is a simple way to determine the rate of a metal acid reaction?
Use a gas syringe to measure the volume of hydrogen gas released.
Metals which react with dilute acids will produce a salt and release hydrogen gas according to the equation below:
metal(s) + acid(aq) salt(aq) + hydrogen(g)

The image below shows the reactions of the metals magnesium, zinc, iron, tin, lead and copper with dilute acid. It would be foolish to add any of the alkali metals from group 1 of the periodic table to acids as their reactions with water are violent enough; so adding them to acid would be considered too dangerous in a classroom environment since the reactions are likely to be violent or even explosive.

For the reactions shown in the image below you can measure the rate or speed of the reaction by simply measuring how quickly the hydrogen gas is produced or even a simple thermometer would give an indication of the amount of energy released and the number of bubbles of hydrogen released would give an indication of the speed of the reaction.


Metal acid reactions, The reactions of various metals with acids in test tubes is shown.
You can see from the image that the fastest reaction is with the magnesium metal; and that as the metals become less reactive as we move from magnesium to zinc all the way down to the unreactive copper metal; from the image you can see that the rate of production of hydrogen gas decreases; that is the rate of reaction slows down.

Equations for metal acid reactions

You should already know that: Info graphic explaining how a salt is formed from an acid.

Salts and acids

The table below lists the three common strong acids that you are likely to use in the lab and the names of the salts they form when they react.

Acid Formula Salt formed
hydrochloric HCl chloride
sulfuric H2SO4 sulfate
nitric HNO3 nitrate

Writing equations for metal acid reactions

Below are some example word and symbolic equations for the reactions of acids with metals, study these equations and check that you are able to write word and balanced symbolic equations for these reactions, try the examples in the practice questions to test your understanding. If you need help with working out the formulae for acids and salts then visit the page on finding the formula. You should also read the page on acids if you are unsure of the properties of acids and salts.

Reactions of metals and hydrochloric acid

1. magnesium

magnesium(s) + hydrochloric acid(aq) magnesium chloride(aq) + hydrogen(g)
Mg(s) + 2HCl(aq) MgCl2(aq) + H2(g)

2. calcium

calcium(s) + hydrochloric acid(aq) calcium chloride(aq) + hydrogen(g)
Ca(s) + 2HCl(aq) CaCl2(aq) + H2(g)

You can see that hydrochloric acid always produces a salt called a chloride, in each of the symbolic equations above all that is happening is the H+ ion present in the acid is replaced by a metal, you can think of these reactions as a type of displacement reaction where the metal displaces the hydrogen ions (H+) in the acid. In this case the metals magnesium and calcium displace or remove the hydrogen ions (H+) that were present in the acid to form the salt while the hydrogen ions (H+) are reduced to form hydrogen gas.

Using sulfuric acid

1. magnesium

magnesium(s) + sulfuric acid(aq) magnesium sulfate(aq) + hydrogen(g)
Mg(s) + H2SO4(aq) Mg SO4(aq) + H2(g)

2. calcium

calcium(s) + sulfuric acid(aq) calcium sulfate(aq) + hydrogen(g)
Ca(s) + H2SO4(aq) Ca SO4(aq) + H2(g)

You can see that when sulfuric acid reacts with a metal it always forms a salt called a sulfate, exactly the same reaction happens here as in the above reactions with hydrochloric acid, the hydrogen ions (H+) in the sulfuric acid are replaced by the metal to form the salts called sulfates; and the hydrogen ions (H+) in the acid are reduced to form hydrogen gas.

Using nitric acid

1. magnesium

magnesium(s) + nitric acid(aq) magnesium nitrate(aq) + hydrogen(g)
Mg(s) + 2HNO3(aq) Mg(NO3)2(aq) + H2(g)

You can see that nitric acid always produces a salt called a nitrate.

Self-check

Match the acid with the salt it forms. Simply click the acid and then the name of the salt it forms, press the check answer button when your done.


Click an acid, then click the correct salt type. There are distractors in the salt grid.

Acids

Hydrochloric acid (HCl)
Sulfuric acid (H2SO4)
Nitric acid (HNO3)
Carbonic acid (H2CO3)
Ethanoic acid (CH3COOH)
Phosphoric acid (H3PO4)

Salt Types

Chloride
Sulfate
Nitrate
Carbonate
Ethanoate
Phosphate
Chlorate
Hydrogensulfate
Nitrite
Hydrogencarbonate

Self-check: Acid metal reactions equations

Complete the symbolic equations in the activity below by simply clicking the choices button to fill the blanks or blanks in the symbolic equations. Press the check answer button or the reveal answer button if your totally stuck.


Complete the Equations below:

Score: 0 / 0

Tap a choice to auto-fill the blank(s) in the equation below. Press the check answers button for green/red feedback, or Reveal answers (no score).


Summary

In the reactions of metals with acid the metal is always oxidised; that is they lose electrons e.g. consider the metal magnesium; it is an alkaline earth metal in group 2 of the periodic table; this means it has 2 electrons in its last shell, so it will lose these 2 outer electrons in its reactions to form a metal ion with a 2+ charge.

Mg(s) → Mg2+(aq) + 2e   This is an oxidation reaction.

The acid contains H+(aq) ions and these gain electrons to form hydrogen gas:

2H+(aq) + 2eH2(g)  This is a reduction reaction.

The metal is oxidised and the hydrogen ions (H+) are reduced; so this is an example of a redox reaction. A redox reaction is one where one substance is reduced (gains electrons) and another substance is oxidised (loses electrons)


Key Points


Practice questions

Check your understanding - Questions on metal acid reactions

Check your understanding - Additional questions on metal acid reactions

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